Literature DB >> 12599494

The first immobilization of pyridine-bis(oxazoline) chiral ligands.

Alfonso Cornejo1, José M Fraile, José I García, Eduardo García-Verdugo, María J Gil, Gorka Legarreta, Santiago V Luis, Víctor Martínez-Merino, José A Mayoral.   

Abstract

[formula: see text] A chiral pyridine-bis(oxazoline) ligand, functionalized with a vinyl group in the pyridine ring, can be polymerized with styrene and divinylbenzene to obtain supported chiral ligands. As proof of the usefulness of this supported ligands, the corresponding ruthenium complexes are catalysts for the cyclopropanation reaction of styrene with ethyl diazoacetate with up to 85% ee.

Entities:  

Year:  2002        PMID: 12599494     DOI: 10.1021/ol026787a

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  4 in total

1.  Asymmetric intermolecular boron Heck-type reactions via oxidative palladium(II) catalysis with chiral tridentate NHC-amidate-alkoxide ligands.

Authors:  Kyung Soo Yoo; Justin O'Neill; Satoshi Sakaguchi; Richard Giles; Joo Ho Lee; Kyung Woon Jung
Journal:  J Org Chem       Date:  2010-01-01       Impact factor: 4.354

2.  Immobilizing a single pybox ligand onto a library of solid supports.

Authors:  Alfonso Cornejo; José M Fraile; José I García; María J Gil; Víctor Martínez-Merino; José A Mayoral
Journal:  Mol Divers       Date:  2003       Impact factor: 2.943

3.  A fully recyclable heterogenized Cu catalyst for the general carbene transfer reaction in batch and flow.

Authors:  Lourdes Maestre; Erhan Ozkal; Carles Ayats; Álvaro Beltrán; M Mar Díaz-Requejo; Pedro J Pérez; Miquel A Pericàs
Journal:  Chem Sci       Date:  2014-11-28       Impact factor: 9.825

4.  Recyclable heterogeneous metal foil-catalyzed cyclopropenation of alkynes and diazoacetates under solvent-free mechanochemical reaction conditions.

Authors:  Longrui Chen; Devonna Leslie; Michael G Coleman; James Mack
Journal:  Chem Sci       Date:  2018-04-24       Impact factor: 9.825

  4 in total

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