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Literature DB >> 12585422

Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA complexes [(C5R5)RuCl(PTA)2] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane).

Dina N Akbayeva¹, Luca Gonsalvi, Werner Oberhauser, Maurizio Peruzzini, Francesco Vizza, Peter Brüggeller, Antonio Romerosa, Gianni Sava, Alberta Bergamo.

Abstract

The new water soluble ruthenium complexes [(C5R5)RuCl(PTA)2] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane) were synthesised and characterised. Their evaluation as regioselective catalysts for hydrogenation of unsaturated ketones in aqueous biphasic conditions and as cytotoxic agents towards the TS/A adenocarcinoma cell line is briefly presented.

Entities: Chemical Disease

Mesh：

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Year: 2003 PMID： 12585422 DOI： 10.1039/b210102e

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

3 in total

Review 1. Scope of organometallic compounds based on transition metal-arene systems as anticancer agents: starting from the classical paradigm to targeting multiple strategies.

Authors: Mehvash Zaki; Suboot Hairat; Elham S Aazam
Journal: RSC Adv Date: 2019-01-24 Impact factor: 4.036

2. Investigating the reactivity of neutral water-soluble Ru(ii)-PTA carbonyls towards the model imine ligands pyridine and 2,2'-bipyridine.

Authors: Federica Battistin; Alessio Vidal; Gabriele Balducci; Enzo Alessio
Journal: RSC Adv Date: 2020-07-16 Impact factor: 4.036

3. Insights into the κ-P,N Coordination of 1,3,5-Triaza-7-phosphaadamantane and Derivatives: κ-P,N-Heterometallic Complexes and a ¹⁵N Nuclear Magnetic Resonance Survey.

Authors: Andrés Alguacil; Franco Scalambra; Antonio Romerosa
Journal: Inorg Chem Date: 2022-04-04 Impact factor: 5.436

3 in total

Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA complexes [(C5R5)RuCl(PTA)2] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane).

Review 1. Scope of organometallic compounds based on transition metal-arene systems as anticancer agents: starting from the classical paradigm to targeting multiple strategies.

2. Investigating the reactivity of neutral water-soluble Ru(ii)-PTA carbonyls towards the model imine ligands pyridine and 2,2'-bipyridine.

3. Insights into the κ-P,N Coordination of 1,3,5-Triaza-7-phosphaadamantane and Derivatives: κ-P,N-Heterometallic Complexes and a 15N Nuclear Magnetic Resonance Survey.

3. Insights into the κ-P,N Coordination of 1,3,5-Triaza-7-phosphaadamantane and Derivatives: κ-P,N-Heterometallic Complexes and a ¹⁵N Nuclear Magnetic Resonance Survey.