Literature DB >> 12578972

The origin of the boson peak and thermal conductivity plateau in low-temperature glasses.

Vassiliy Lubchenko1, Peter G Wolynes.   

Abstract

We argue that the intrinsic glassy degrees of freedom in amorphous solids giving rise to the thermal conductivity plateau and the "boson peak" in the heat capacity at moderately low temperatures are directly connected to those motions giving rise to the two-level-like excitations seen at still lower temperatures. These degrees of freedom can be thought of as strongly anharmonic transitions between the local minima of the glassy energy landscape that are accompanied by ripplon-like domain wall motions of the glassy mosaic structure predicted to occur at T(g) by the random first-order transition theory. The energy spectrum of the vibrations of the mosaic depends on the glass transition temperature, the Debye frequency, and the molecular length scale. The resulting spectrum reproduces the experimental low-temperature boson peak. The "nonuniversality" of the thermal conductivity plateau depends on k(B)T(g)omega(D) and arises from calculable interactions with the phonons.

Entities:  

Year:  2003        PMID: 12578972      PMCID: PMC149863          DOI: 10.1073/pnas.252786999

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN: 0027-8424            Impact factor:   11.205


  7 in total

1.  Fragilities of liquids predicted from the random first order transition theory of glasses.

Authors:  X Xia; P G Wolynes
Journal:  Proc Natl Acad Sci U S A       Date:  2000-03-28       Impact factor: 11.205

2.  Microscopic theory of heterogeneity and nonexponential relaxations in supercooled liquids.

Authors:  X Xia; P G Wolynes
Journal:  Phys Rev Lett       Date:  2001-06-11       Impact factor: 9.161

3.  Intrinsic quantum excitations of low temperature glasses.

Authors:  V Lubchenko; P G Wolynes
Journal:  Phys Rev Lett       Date:  2001-10-19       Impact factor: 9.161

4.  Vibrational spectrum of topologically disordered systems.

Authors:  T S Grigera; V Martín-Mayor; G Parisi; P Verrocchio
Journal:  Phys Rev Lett       Date:  2001-08-02       Impact factor: 9.161

5.  Lower limit to the thermal conductivity of disordered crystals.

Authors: 
Journal:  Phys Rev B Condens Matter       Date:  1992-09-01

6.  Thermal conductivity of amorphous solids.

Authors: 
Journal:  Phys Rev B Condens Matter       Date:  1986-10-15

7.  Direct observation of molecular cooperativity near the glass transition.

Authors:  E V Russell; N E Israeloff
Journal:  Nature       Date:  2000-12-07       Impact factor: 49.962

  7 in total
  4 in total

1.  A unified model of protein dynamics.

Authors:  Hans Frauenfelder; Guo Chen; Joel Berendzen; Paul W Fenimore; Helén Jansson; Benjamin H McMahon; Izabela R Stroe; Jan Swenson; Robert D Young
Journal:  Proc Natl Acad Sci U S A       Date:  2009-02-27       Impact factor: 11.205

2.  Anomalous properties of the acoustic excitations in glasses on the mesoscopic length scale.

Authors:  Giulio Monaco; Stefano Mossa
Journal:  Proc Natl Acad Sci U S A       Date:  2009-09-23       Impact factor: 11.205

3.  Rigidity, secondary structure, and the universality of the boson peak in proteins.

Authors:  Stefania Perticaroli; Jonathan D Nickels; Georg Ehlers; Alexei P Sokolov
Journal:  Biophys J       Date:  2014-06-17       Impact factor: 4.033

4.  Role of Anharmonic Interactions for Vibration Density of States in α-Cristobalite.

Authors:  Yongda Huang; Jian Zhou; Guanjie Wang; Zhimei Sun
Journal:  Materials (Basel)       Date:  2021-01-29       Impact factor: 3.623

  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.