| Literature DB >> 12568600 |
Juan Cámpora1, Celia M Maya, Pilar Palma, Ernesto Carmona, Enrique Gutiérrez-Puebla, Caridad Ruiz.
Abstract
The often facile C-/O-tautomerization of transition metal enolates is severely hindered in the cyclic Ni complexes 1 and 2, allowing the study of their individual reactivities. At room temperature only the O-bound tautomer, 2, reacts with aldehydes, giving rise to the corresponding addition products.Entities:
Year: 2003 PMID： 12568600 DOI： 10.1021/ja028711f
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419