Literature DB >> 12568582

Highly regioselective functionalization of aliphatic carbon-hydrogen bonds with a perbromohomoscorpionate copper(I) catalyst.

Ana Caballero1, M Mar Díaz-Requejo, Tomás R Belderraín, M Carmen Nicasio, Swiatoslaw Trofimenko, Pedro J Pérez.   

Abstract

The complex Tp(Br3)Cu(NCMe) (1) is an excellent catalyst for the regioselective carbene transfer reaction to tertiary C-H bonds of hydrocarbons, at room temperature, using the readily available ethyl diazoacetate (EDA) as the carbene source.

Entities:  

Year:  2003        PMID： 12568582     DOI： 10.1021/ja0291484

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  4 in total

1.  Conversion of alkanes to linear alkylsilanes using an iridium-iron-catalysed tandem dehydrogenation-isomerization-hydrosilylation.

Authors:  Xiangqing Jia; Zheng Huang
Journal:  Nat Chem       Date:  2015-12-21       Impact factor: 24.427

Review 2.  Challenges and opportunities for alkane functionalisation using molecular catalysts.

Authors:  Xinxin Tang; Xiangqing Jia; Zheng Huang
Journal:  Chem Sci       Date:  2017-11-09       Impact factor: 9.825

3.  Introducing the Catalytic Amination of Silanes via Nitrene Insertion.

Authors:  Anabel M Rodríguez; Jorge Pérez-Ruíz; Francisco Molina; Ana Poveda; Raúl Pérez-Soto; Feliu Maseras; M Mar Díaz-Requejo; Pedro J Pérez
Journal:  J Am Chem Soc       Date:  2022-06-01       Impact factor: 16.383

Review 4.  Recent advances in C(sp(3))-H bond functionalization via metal-carbene insertions.

Authors:  Bo Wang; Di Qiu; Yan Zhang; Jianbo Wang
Journal:  Beilstein J Org Chem       Date:  2016-04-25       Impact factor: 2.883
  4 in total

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