Literature DB >> 12553805

Reaction of elemental sulfur with a copper(I) complex forming a trans-mu-1,2 end-on disulfide complex: new directions in copper-sulfur chemistry.

Matthew E Helton1, Peng Chen, Partha P Paul, Zoltán Tyeklár, Roger D Sommer, Lev N Zakharov, Arnold L Rheingold, Edward I Solomon, Kenneth D Karlin.   

Abstract

Elemental sulfur (S8) was found to react with [(TMPA)CuI(CH3CN)]+ to form the trans-mu-1,2 end-on disulfide complex [(TMPA)Cu-S-S-Cu(TMPA)]2+. The X-ray structure of this centrosymmetric disulfide complex shows a Cu(1)-S(1) bond length of 2.280(2) A and a S(1)-S(1A) bond length of 2.044(4) A.

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Year:  2003        PMID： 12553805     DOI： 10.1021/ja027574j

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  9 in total

Review 1.  Using synthetic chemistry to understand copper protein active sites: a personal perspective.

Authors:  William B Tolman
Journal:  J Biol Inorg Chem       Date:  2006-01-27       Impact factor: 3.358

2.  Ligand structural effects on Cu2S2 bonding and reactivity in side-on disulfido-bridged dicopper complexes.

Authors:  Eric C Brown; Itsik Bar-Nahum; John T York; Nermeen W Aboelella; William B Tolman
Journal:  Inorg Chem       Date:  2007-01-22       Impact factor: 5.165

3.  Molecular oxygen and sulfur reactivity of a cyclotriveratrylene derived trinuclear copper(I) complex.

Authors:  Debabrata Maiti; Julia S Woertink; Reza A Ghiladi; Edward I Solomon; Kenneth D Karlin
Journal:  Inorg Chem       Date:  2009-09-07       Impact factor: 5.165

4.  Laser-Induced Dynamics of Peroxodicopper(II) Complexes Vary with the Ligand Architecture. One-Photon Two-Electron O2 Ejection and Formation of Mixed-Valent Cu(I)Cu(II)-Superoxide Intermediates.

Authors:  Claudio Saracini; Kei Ohkubo; Tomoyoshi Suenobu; Gerald J Meyer; Kenneth D Karlin; Shunichi Fukuzumi
Journal:  J Am Chem Soc       Date:  2015-12-11       Impact factor: 15.419

5.  Synthesis and spectroscopic identification of a mu-1,2-disulfidodinickel complex.

Authors:  Matthew T Kieber-Emmons; Katherine M Van Heuvelen; Thomas C Brunold; Charles G Riordan
Journal:  J Am Chem Soc       Date:  2009-01-21       Impact factor: 15.419

6.  X-ray absorption spectroscopic and theoretical studies on (L)2[Cu2(S2)n]2+ complexes: disulfide versus disulfide(*1-) bonding.

Authors:  Ritimukta Sarangi; John T York; Matthew E Helton; Kiyoshi Fujisawa; Kenneth D Karlin; William B Tolman; Keith O Hodgson; Britt Hedman; Edward I Solomon
Journal:  J Am Chem Soc       Date:  2007-12-13       Impact factor: 15.419

7.  Copper-Sulfur Complexes Supported by N-Donor Ligands: Towards Models of the Cu(Z) Site in Nitrous Oxide Reductase.

Authors:  John T York; Itsik Bar-Nahum; William B Tolman
Journal:  Inorganica Chim Acta       Date:  2008-03-03       Impact factor: 2.545

8.  Chemical issues addressing the construction of the distal Ni[cysteine-glycine-cysteine]2- site of acetyl CoA synthase: why not copper?

Authors:  Kayla N Green; Scott M Brothers; Boram Lee; Marcetta Y Darensbourg; David A Rockcliffe
Journal:  Inorg Chem       Date:  2009-04-06       Impact factor: 5.165

9.  Constructing Binder- and Carbon Additive-Free Organosulfur Cathodes Based on Conducting Thiol-Polymers through Electropolymerization for Lithium-Sulfur Batteries.

Authors:  Jiaoyi Ning; Hongtao Yu; Shilin Mei; Yannik Schütze; Sebastian Risse; Nikolay Kardjilov; André Hilger; Ingo Manke; Annika Bande; Victor G Ruiz; Joachim Dzubiella; Hong Meng; Yan Lu
Journal:  ChemSusChem       Date:  2022-05-30       Impact factor: 9.140
  9 in total

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