Literature DB >> 12542337

Absolute configuration of a tetrahydrophenanthrene from Heliotropium ovalifolium by LC-NMR of its Mosher esters.

David Guilet1, Alain Guntern, Jean-Robert Ioset, Emerson F Queiroz, Karine Ndjoko, Chris M Foggin, Kurt Hostettmann.   

Abstract

A new tetrahydrophenanthrene (1, (1R,2R)-1-hydroxy-2-methoxy-6,9-dimethyl-2,3-dihydrophenanthren-4(1H)-one (heliophenanthrone)) has been isolated from the aerial parts of Heliotropium ovalifolium. Its structure was elucidated on the basis of spectroscopic data, and the absolute configuration of the asymmetric centers was determined from LC-NMR data of the Mosher ester derivatives.

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Year:  2003        PMID: 12542337     DOI: 10.1021/np020366k

Source DB:  PubMed          Journal:  J Nat Prod        ISSN: 0163-3864            Impact factor:   4.050


  3 in total

1.  Three New Sesquiterpenoids from the Algal-Derived Fungus Penicillium chermesinum EN-480.

Authors:  Xue-Yi Hu; Xiao-Ming Li; Sui-Qun Yang; Hui Liu; Ling-Hong Meng; Bin-Gui Wang
Journal:  Mar Drugs       Date:  2020-04-07       Impact factor: 5.118

Review 2.  Indigenous Uses, Phytochemical Analysis, and Anti-Inflammatory Properties of Australian Tropical Medicinal Plants.

Authors:  Karma Yeshi; Gerry Turpin; Tenzin Jamtsho; Phurpa Wangchuk
Journal:  Molecules       Date:  2022-06-15       Impact factor: 4.927

3.  Absolute Configuration Determination of Retroflexanone Using the Advanced Mosher Method and Application of HPLC-NMR.

Authors:  Caleb Singleton; Robert Brkljača; Sylvia Urban
Journal:  Mar Drugs       Date:  2018-06-12       Impact factor: 5.118

  3 in total

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