Literature DB >> 12536817

Nucleophilic substitution of alkylchlorodihydro[60]fullerenes: thermodynamic stabilities of alkylated C60 cation intermediates.

Toshikazu Kitagawa1, Yangsoo Lee, Masaaki Hanamura, Harumi Sakamoto, Hirofumi Konno, Ken'ichi Takeuchi, Koichi Komatsu.   

Abstract

Thermodynamic stabilities of alkylated C60 cations (RC60+) were determined based on the activation free energies of SN1 solvolysis of the title compounds, indicating that these cations have stabilities comparable to that of the tert-butyl cation.

Entities:  

Year:  2002        PMID: 12536817     DOI: 10.1039/b210126b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

Review 1.  Chemistry of fullerene epoxides: synthesis, structure, and nucleophilic substitution-addition reactivity.

Authors:  Yusuke Tajima; Kazumasa Takeshi; Yasuo Shigemitsu; Youhei Numata
Journal:  Molecules       Date:  2012-05-25       Impact factor: 4.411

  1 in total

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