Literature DB >> 12534303

Supramolecular systems as microreactors: control of product selectivity in organic phototransformation.

Chen-Ho Tung1, Li-Zhu Wu, Li-Ping Zhang, Bin Chen.   

Abstract

This Account reviews the developments in microreactor-controlled selectivity in organic phototransformation. Photocycloaddition of alpha,omega-diaryl compounds with long flexible chains within Y-type zeolite and low-density polyethylene films leads to formation of intramolecular cyclomers to the exclusion of intermolecular products. ZSM-5 zeolite, Nafion membranes, and vesicles as hosts direct photosensitized oxidation of alkenes selectively toward either the energy-transfer-mediated or the electron-transfer-mediated products. Zeolites, Nafion membranes, and microemulsions as microreactors remarkably control chemo-, regio-, and stereoselectivity in the photochemical reaction of phenyl phenylacetates, photocycloaddition of anthracenes, and photocyclization of azobenzene and stilbazole.

Entities:  

Year:  2003        PMID： 12534303     DOI： 10.1021/ar010141l

Source DB:  PubMed          Journal:  Acc Chem Res        ISSN： 0001-4842            Impact factor:   22.384


  9 in total

1.  Norrish' type I and II reactions and their role in the building of photochemical science.

Authors:  Angelo Albini
Journal:  Photochem Photobiol Sci       Date:  2021-01-02       Impact factor: 3.982

2.  Induced selectivity in the photochemistry of estrone derivatives in sustainable and micellar environment: preparative and mechanistic studies.

Authors:  Matías I Quindt; Gabriel F Gola; J A Ramirez; Sergio M Bonesi
Journal:  Photochem Photobiol Sci       Date:  2021-10-01       Impact factor: 4.328

3.  Density functional investigations on 2-naphthalenecarbonitrile dimerization within cucurbit[8]uril cavitand.

Authors:  Swarada R Peerannawar; Soniya S Rao; Shridhar P Gejji
Journal:  J Mol Model       Date:  2014-01-25       Impact factor: 1.810

Review 4.  Organic Zeolite Analogues Based on Multi-Component Liquid Crystals: Recognition and Transformation of Molecules within Constrained Environments.

Authors:  Yasuhiro Ishida
Journal:  Materials (Basel)       Date:  2011-01-11       Impact factor: 3.623

5.  Synthesis and characterization of novel dendrons bearing amino-nitro-substituted azobenzene units and oligo(ethylene glycol) spacers: thermal, optical properties, Langmuir blodgett films and liquid-crystalline behaviour.

Authors:  Jesús Ortíz-Palacios; Efraín Rodríguez-Alba; Mayra Avelar; Ana Martínez; Maria Del Pilar Carreón-Castro; Ernesto Rivera
Journal:  Molecules       Date:  2013-01-25       Impact factor: 4.411

6.  Density Functional Theory Applied to Excited State Intramolecular Proton Transfer in Imidazole-, Oxazole-, and Thiazole-Based Systems.

Authors:  Fabricio de Carvalho; Maurício D Coutinho Neto; Fernando H Bartoloni; Paula Homem-de-Mello
Journal:  Molecules       Date:  2018-05-21       Impact factor: 4.411

7.  Supramolecular-induced regiocontrol over the photochemical [4 + 4] cyclodimerization of NHC- or azole-substituted anthracenes.

Authors:  Sha Bai; Li-Li Ma; Tao Yang; Fang Wang; Li-Feng Wang; F Ekkehardt Hahn; Yao-Yu Wang; Ying-Feng Han
Journal:  Chem Sci       Date:  2020-12-17       Impact factor: 9.825

8.  A pyrene- and phosphonate-containing fluorescent probe as guest molecule in a host polymer matrix.

Authors:  Elise Villemin; Benjamin Elias; Michel Devillers; Jacqueline Marchand-Brynaert
Journal:  Molecules       Date:  2013-02-01       Impact factor: 4.411

9.  Freeze the dynamicity: charge transfer complexation assisted control over the reaction pathway.

Authors:  Nilotpal Singha; Basab Kanti Das; Bapan Pramanik; Saurav Das; Debapratim Das
Journal:  Chem Sci       Date:  2019-09-09       Impact factor: 9.825
  9 in total

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