Literature DB >> 12526452

The first organo-templated cobalt phosphate with a zeolite topology.

H M Yuan1, J S Chen, G S Zhu, J Y Li, J H Yu, G D Yang, R R Xu.   

Abstract

An organic molecule containing cobalt phosphate (denoted CoPO-GIS) which is isostructural with the zeolite gismondine has been synthesized under solvothermal conditions by using [Co(en)3]Cl3 and phosphoric acid as the reactants and ethylene glycol as the solvent. CoPO-GIS ((H3NCH2CH2NH3)0.5.CoPO4) crystallizes in the monoclinic space group C2/c with a = 14.744(3) A, b = 8.850(3) A, c = 10.062(3) A, beta = 131.609(19) degrees, and Z = 8. The structure consists of a 3-D network of strictly alternating CoO4 and PO4 tetrahedra interconnected by oxygen bridges, and the charge-balancing diprotonated ethylenediamine cations are highly ordered in the cages of the CoPO4 framework. CoPO-GIS is the only amine-containing cobalt phosphate with a known zeolite topology.

Entities:  

Year:  2000        PMID： 12526452     DOI： 10.1021/ic990719b

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  3 in total

1.  Ionothermal synthesis of open-framework metal phosphates with a Kagomé lattice network exhibiting canted anti-ferromagnetism†Electronic supplementary information (ESI) available: Cif files, atomic parameters, X-ray diffraction patterns, IR spectra, TG curves, and thermal ellipsoid plot and atomic label schemes of compound 1-4. See DOI: 10.1039/c4tc00290cClick here for additional data file.

Authors:  Guangmei Wang; Martin Valldor; Bert Mallick; Anja-Verena Mudring
Journal:  J Mater Chem C Mater       Date:  2014-08-04       Impact factor: 7.393

2.  Conventional Cells-The Last Step Toward General Acceptance of Standard Conventional Cells for the Reporting of Crystallographic Data.

Authors:  Alan D Mighell
Journal:  J Res Natl Inst Stand Technol       Date:  2002-08-01

3.  Multifunctional Chiral Three-Dimensional Phosphite Frameworks Showing Dielectric Anomaly and High Proton Conductivity.

Authors:  S S Yu; C Y Xu; X Pan; X Q Pan; H B Duan; H Zhang
Journal:  Front Chem       Date:  2021-12-09       Impact factor: 5.221
  3 in total

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