| Literature DB >> 12517132 |
Shih-Chieh Yin1, Hiltrud Grondey, Pierre Strobel, Huan Huang, Linda F Nazar.
Abstract
The delithiation process in monoclinic Li3V2(PO4)3 has been determined by powder neutron diffraction coupled with 7Li solid-state NMR techniques. Charge ordering of vanadium (V3+/V4+) was observed in Li2V2(PO4)3 as shown by the gray and blue V-O octahedra, respectively, indicating that the electrons are pinned in this phase and hence transport is limited.Entities:
Year: 2003 PMID： 12517132 DOI： 10.1021/ja028973h
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419