| Literature DB >> 12509898 |
J Stephen Clark1, Frederic Marlin, Bastien Nay, Claire Wilson.
Abstract
An advanced intermediate in the synthesis of the phytotoxins cornexistin and hydroxycornexistin has been synthesized. Sequential palladium-mediated sp(2)-sp(3) fragment coupling and ring-closing diene metathesis have been used to construct the nine-membered carbocyclic core found in the natural products. [reaction--see text]Entities:
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Year: 2003 PMID： 12509898 DOI： 10.1021/ol027265y
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005