Literature DB >> 12509890

A 4+3 cycloaddition approach to the synthesis of (+/-)-sterpurene.

Michael Harmata1, Gary J Bohnert.   

Abstract

A synthesis of the sesquiterpene sterpurene is presented. Key steps include a 4+3 cycloaddition reaction and a quasi-Favorskii rearrangement. [reaction--see text]

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Year:  2003        PMID： 12509890     DOI： 10.1021/ol027176l

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Intramolecular thermal allenyne [2 + 2] cycloadditions; facile construction of the 5-6-4 ring core of sterpurene.

Authors:  Timo V Ovaska; Robert E Kyne
Journal:  Tetrahedron Lett       Date:  2008-01-07       Impact factor: 2.415

2.  The catalytic asymmetric Diels-Alder reactions and post-cycloaddition reductive transpositions of 1-hydrazinodienes.

Authors:  Hao Xie; Glenn M Sammis; Eric M Flamme; Christina M Kraml; Erik J Sorensen
Journal:  Chemistry       Date:  2011-09-05       Impact factor: 5.236

3.  Acyclic 1,4-stereocontrol via reductive 1,3-transpositions.

Authors:  Wei Qi; Matthias C McIntosh
Journal:  Org Lett       Date:  2007-12-20       Impact factor: 6.005

4.  Structural complexity through multicomponent cycloaddition cascades enabled by dual-purpose, reactivity regenerating 1,2,3-triene equivalents.

Authors:  Paul A Wender; Dennis N Fournogerakis; Matthew S Jeffreys; Ryan V Quiroz; Fuyuhiko Inagaki; Magnus Pfaffenbach
Journal:  Nat Chem       Date:  2014-04-13       Impact factor: 24.427
  4 in total

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