Literature DB >> 12489965

A new, simple, and selective palladium-catalyzed cleavage of triethylsilyl ethers.

Delphine Rotulo-Sims1, Joëlle Prunet.   

Abstract

[reaction: see text] A simple procedure for the cleavage of triethylsilyl (TES) ethers in the presence of 10 wt % Pd/C in methanol or 95% ethanol is reported. This method allows selective removal of alkyl TES ethers in the presence of aromatic TES ethers or tert-butyldimethylsilyl (TBS) protecting groups.

Entities:  

Year:  2002        PMID： 12489965     DOI： 10.1021/ol0271382

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Chemoselective deprotection of triethylsilyl ethers.

Authors:  Tilak Chandra; William E Broderick; Joan B Broderick
Journal:  Nucleosides Nucleotides Nucleic Acids       Date:  2009-11       Impact factor: 1.381

2.  Illicium sesquiterpenes: divergent synthetic strategy and neurotrophic activity studies.

Authors:  Lynnie Trzoss; Jing Xu; Michelle H Lacoske; William C Mobley; Emmanuel A Theodorakis
Journal:  Chemistry       Date:  2013-03-22       Impact factor: 5.236

3.  C-H-Functionalization logic guides the synthesis of a carbacyclopamine analog.

Authors:  Sebastian Rabe; Johann Moschner; Marina Bantzi; Philipp Heretsch; Athanassios Giannis
Journal:  Beilstein J Org Chem       Date:  2014-07-09       Impact factor: 2.883
  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.