Literature DB >> 12489957

Novel nucleophilic trifluoromethylation of vicinal diol cyclic sulfates.

Naoto Takechi1, Samia Ait-Mohand, Maurice Medebielle, William R Dolbier.   

Abstract

[reaction: see text] A novel method for highly regioselective and stereospecific nucleophilic trifluoromethylation of vicinal diol cyclic sulfates, using the reagent derived from reduction of trifluoromethyl iodide by tetrakis(dimethylamino)ethylene (TDAE), is presented.

Entities:  

Year:  2002        PMID： 12489957     DOI： 10.1021/ol0270374

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Nucleophilic trifluoromethylation of carbonyl compounds: trifluoroacetaldehyde hydrate as a trifluoromethyl source.

Authors:  G K Surya Prakash; Zhe Zhang; Fang Wang; Socrates Munoz; George A Olah
Journal:  J Org Chem       Date:  2013-02-28       Impact factor: 4.354

2.  Interrupting the Barton-McCombie Reaction: Aqueous Deoxygenative Trifluoromethylation of O-Alkyl Thiocarbonates.

Authors:  Zhi-Yun Liu; Silas P Cook
Journal:  Org Lett       Date:  2021-01-14       Impact factor: 6.072

3.  Discovery and development of organic super-electron-donors.

Authors:  John A Murphy
Journal:  J Org Chem       Date:  2014-03-25       Impact factor: 4.354

4.  Reduction of arenediazonium salts by tetrakis(dimethylamino)ethylene (TDAE): efficient formation of products derived from aryl radicals.

Authors:  Mohan Mahesh; John A Murphy; Franck LeStrat; Hans Peter Wessel
Journal:  Beilstein J Org Chem       Date:  2009-01-12       Impact factor: 2.883
  4 in total

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