Literature DB >> 12478752

Electrocatalytic carboxylation of benzyl chlorides at silver cathodes in acetonitrile.

Abdirisak A Isse1, Armando Gennaro.   

Abstract

Silver exhibits powerful electrocatalytic activities towards the reductive carboxylation of benzyl chlorides (RCl): in CO2-saturated CH3CN, reduction of RCl occurs at potentials that are about 0.6 V more positive than those of the same process at Hg or carbon electrodes and gives carboxylic acids in good to excellent yields.

Entities:  

Year:  2002        PMID: 12478752     DOI: 10.1039/b206746c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  6 in total

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Authors:  Ming Yan; Yu Kawamata; Phil S Baran
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2. 

Authors:  Shu-Feng Zhao; Huan Wang; Yang-Chun Lan; Xiao Liu; Jia-Xing Lu; Jie Zhang
Journal:  J Electroanal Chem (Lausanne)       Date:  2012-01-01       Impact factor: 4.464

Review 3.  Electrocarboxylation: towards sustainable and efficient synthesis of valuable carboxylic acids.

Authors:  Roman Matthessen; Jan Fransaer; Koen Binnemans; Dirk E De Vos
Journal:  Beilstein J Org Chem       Date:  2014-10-27       Impact factor: 2.883

4.  Silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with CO2.

Authors:  La-Xia Wu; Ying-Guo Zhao; Ye-Bin Guan; Hui Wang; Yang-Chun Lan; Huan Wang; Jia-Xing Lu
Journal:  RSC Adv       Date:  2019-10-15       Impact factor: 4.036

5.  Electrocarboxylation of 1-chloro-(4-isobutylphenyl)ethane with a silver cathode in ionic liquids: an environmentally benign and efficient way to synthesize Ibuprofen.

Authors:  Silvia Mena; Jessica Sanchez; Gonzalo Guirado
Journal:  RSC Adv       Date:  2019-05-14       Impact factor: 4.036

6.  Fixation of CO2 along with bromopyridines on a silver electrode.

Authors:  Yingtian Zhang; Shuxian Yu; Peipei Luo; Shisong Xu; Xianxi Zhang; Huawei Zhou; Jiyuan Du; Jie Yang; Nana Xin; Yuxia Kong; Junhai Liu; Baoli Chen; Jiaxing Lu
Journal:  R Soc Open Sci       Date:  2018-08-15       Impact factor: 2.963

  6 in total

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