| Literature DB >> 12467433 |
S Chandrasekhar1, Ch Raji Reddy, B Nagendra Babu.
Abstract
The polymethylhydrosiloxane-B(C(6)F(5))(3) combination is found to be a versatile carbonyl defunctionalization system under mild and rapid conditions. For the first time, B(C(6)F(5))(3) has been used as a nonconventional Lewis acid catalyst to activate PMHS. Aromatic and aliphatic carbonyl compounds were effectively reduced to give the corresponding alkanes in high yields.Entities:
Year: 2002 PMID： 12467433 DOI： 10.1021/jo0204045
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354