Literature DB >> 12466618

C-H...N and C-H...pi interactions in 2-ethoxy-4,6-diphenylpyridine-3-carbonitrile.

Urmila H Patel1, Chaitanya G Dave, Mukesh M Jotani, Hetal C Shah.   

Abstract

The title compound, C(20)H(16)N(2)O, has two molecules in the asymmetric unit and the crystal structure shows that the central pyridine ring of each molecule has a flat boat conformation. The terminal C atom in one of the molecules is disordered over two positions, with relative occupancies of 0.594 (14) and 0.398 (14). Intermolecular C-H.N and C-H.pi interactions and pi-pi stacking, along with intramolecular C-H.N and C-H.pi interactions, help to stabilize the structure.

Entities:  

Year:  2002        PMID: 12466618     DOI: 10.1107/s0108270102018383

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  2 in total

1.  2-Meth-oxy-4,6-di-phenyl-nicotino-nitrile.

Authors:  Joel T Mague; Alaa A-M Abdel-Aziz; Adel S El-Azab; Ibrahim A Al-Swaidan
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2014-01-31

2.  2-Eth-oxy-4-(4-methyl-phen-yl)-6-phenyl-pyridine-3-carbonitrile.

Authors:  Shaaban K Mohamed; Mehmet Akkurt; Antar A Abdelhamid; Kuldip Singh; Mahoud A A El-Remaily
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-07-18
  2 in total

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