Literature DB >> 12452705

Novel 1,4-palladium migration in organopalladium intermediates derived from o-iodobiaryls.

Marino A Campo1, Richard C Larock.   

Abstract

A novel 1,4-palladium migration in organopalladium intermediates derived from o-iodobiaryls has been observed under modified Heck reaction conditions. This migration process can be switched "on" or "off" by simply choosing the appropriate reaction conditions.

Entities:  

Year:  2002        PMID： 12452705     DOI： 10.1021/ja027548l

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  2 in total

1.  Marine furanocembranoids-inspired macrocycles enabled by Pd-catalyzed unactivated C(sp3)-H olefination mediated by donor/donor carbenes.

Authors:  Jiping Hao; Xueying Guo; Shijun He; Zhongliang Xu; Lu Chen; Zhongyu Li; Bichao Song; Jianping Zuo; Zhenyang Lin; Weibo Yang
Journal:  Nat Commun       Date:  2021-02-26       Impact factor: 14.919

2.  Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift.

Authors:  Yinghua Yu; Pushkin Chakraborty; Jinshuai Song; Lei Zhu; Chunsen Li; Xueliang Huang
Journal:  Nat Commun       Date:  2020-01-23       Impact factor: 14.919
  2 in total

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