Literature DB >> 12443409

Onset of metallic behavior in magnesium clusters.

Owen C Thomas1, Weijun Zheng, Shoujun Xu, Kit H Bowen, Moshe Shiloh.   

Abstract

We have measured the photoelectron spectra of mass-selected magnesium cluster anions, Mg- n, over the size range, n=3-35. Their s-p band gaps were observed to close at n=18, signaling the onset of metallic behavior. Electronic shell structure was implicated by gap "reopenings" and mass spectral magic numbers. Complementary calculations are presented in the companion paper [P. H. Acioli and J. Jellinek, Phys. Rev. Lett. 89, 213402 (2002)]].

Entities:  

Year:  2002        PMID： 12443409     DOI： 10.1103/PhysRevLett.89.213403

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN： 0031-9007            Impact factor:   9.161


  8 in total

Review 1.  Clusters: a bridge across the disciplines of physics and chemistry.

Authors:  Puru Jena; A W Castleman
Journal:  Proc Natl Acad Sci U S A       Date:  2006-07-11       Impact factor: 11.205

Review 2.  Highly fluorescent noble-metal quantum dots.

Authors:  Jie Zheng; Philip R Nicovich; Robert M Dickson
Journal:  Annu Rev Phys Chem       Date:  2007       Impact factor: 12.703

3.  Material witness: The smallest metals.

Authors:  Philip Ball
Journal:  Nat Mater       Date:  2011-03       Impact factor: 43.841

4.  Quantum Chemistry Study on the Structures and Electronic Properties of Bimetallic Ca2-Doped Magnesium Ca2Mgn (n = 1-15) Clusters.

Authors:  Chenggang Li; Yingqi Cui; Hao Tian; Baozeng Ren; Qingyang Li; Yuanyuan Li; Hang Yang
Journal:  Nanomaterials (Basel)       Date:  2022-05-12       Impact factor: 5.719

5.  Density functional theory study of small X-doped Mg(n) (X = Fe, Co, Ni, n = 1-9) bimetallic clusters: equilibrium structures, stabilities, electronic and magnetic properties.

Authors:  Fanjie Kong; Yanfei Hu
Journal:  J Mol Model       Date:  2014-02-18       Impact factor: 1.810

6.  Many Mg-Mg bonds form the core of the Mg16Cp*8Br4K cluster anion: the key to a reassessment of the Grignard reagent (GR) formation process?

Authors:  T Kruczyński; F Henke; M Neumaier; K H Bowen; H Schnöckel
Journal:  Chem Sci       Date:  2015-11-26       Impact factor: 9.825

7.  Nanomaterials design for super-degenerate electronic state beyond the limit of geometrical symmetry.

Authors:  Naoki Haruta; Takamasa Tsukamoto; Akiyoshi Kuzume; Tetsuya Kambe; Kimihisa Yamamoto
Journal:  Nat Commun       Date:  2018-09-14       Impact factor: 14.919

8.  Predicting the Photoelectron Spectra of Quasi Octahedral Al6Mo- Cluster.

Authors:  Paulo H Acioli
Journal:  ChemistryOpen       Date:  2020-05-04       Impact factor: 2.911
  8 in total

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