Literature DB >> 12430438

Tris(1-4-eta 4-anthracene)niobate(1-), the first polyaromatic hydrocarbon complex of niobium.

William W Brennessel1, John E Ellis, Sergey N Roush, Brian R Strandberg, Oliver E Woisetschläger, Victor G Young.   

Abstract

The first tris(arene)niobium complex, [Nb(1-4-eta 4-anthracene)3]-, has been obtained by the sodium or potassium anthracene reduction of NbCl4(THF)2, structurally characterized by X-ray analysis and shown to undergo facile anthracene displacement reactions in the presence of excess CO, PF3, 1,3,5,7-cyclooctatetraene and P(OMe)3.

Entities:  

Year:  2002        PMID: 12430438     DOI: 10.1039/b207062f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  (1,4,7,10,13,16-Hexaoxa-cyclo-octa-decane-κ(6) O)bis-(tetra-hydro-furan-κO)potassium bis-[(1,2,3,4-η)-anthracene]cobalt(-I) tetra-hydro-furan monosolvate.

Authors:  Haiyan He; Wilhelm Klein; Thomas F Fässler
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-12-07
  1 in total

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