Literature DB >> 12430413

Hammett analysis of a C-C hydrolase-catalysed reaction using synthetic 6-aryl-2-hydroxy-6-ketohexa-2,4-dienoic acid substrates.

Damian M Speare1, Petra Olf, Timothy D H Bugg.   

Abstract

A Hammett plot (rho = -0.71) has been measured for C-C hydrolase enzyme BphD from Pseudomonas LB400, using six 6-aryl-2-hydroxy-6-ketohexa-2,4-dienoic acids synthesised by a Heck coupling strategy.

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Year:  2002        PMID： 12430413     DOI： 10.1039/b208168g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  1 in total

1.  Kinetic and structural insight into the mechanism of BphD, a C-C bond hydrolase from the biphenyl degradation pathway.

Authors:  Geoff P Horsman; Jiyuan Ke; Shaodong Dai; Stephen Y K Seah; Jeffrey T Bolin; Lindsay D Eltis
Journal:  Biochemistry       Date:  2006-09-19       Impact factor: 3.162
  1 in total

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