| Literature DB >> 12423092 |
Orazio Taglialatela-Scafati1, Urmila Deo-Jangra, Martha Campbell, Michel Roberge, Raymond J Andersen.
Abstract
The known antimitotic agent eleutherobin and the briarane diterpenoids erythrolides A and B have been isolated from cultured specimens of Erythropodium caribaeorum in amounts comparable to those reported from wild-harvested reef animals. The novel diterpenoid aquariolide A, having an unprecedented highly rearranged carbon skeleton (named aquariane), has also been found. The aquariane skeleton can be formally derived from the briarane skeleton by sequential di-pi-methane and vinyl-cyclopropane rearrangements. [structure: see text]Entities:
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Year: 2002 PMID： 12423092 DOI： 10.1021/ol026831m
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005