| Literature DB >> 12398507 |
Zbigniew Grobelny1, Andrzej Stolarzewicz, Barbara Morejko-Buz, Richard A Bartsch, Kazuhiro Yamato, Fernando A Fernandez, Adalbert Maercker.
Abstract
Cyclohexano-15-crown-5, cyclohexano-18-crown-6, dicyclohexano-15-crown-5, and dicyclohexano-18-crown-6, but not dicylohexano-16-crown-5, in THF dissolve potassium metal to form dark blue potassium alkalide solutions at ambient temperature. On standing, the potassium alkalide complexes decompose and the solutions turn colorless at differing rates. Identification of the products provides insight into the decomposition mechanism.Entities:
Year: 2002 PMID： 12398507 DOI： 10.1021/jo026086r
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354