Literature DB >> 12381181

Interconversion between bis(mu-thiolato)dicopper(II) and disulfide-bridged dicopper(I) complexes mediated by chloride ion.

Yoshiki Ueno1, Yoshimitsu Tachi, Shinobu Itoh.   

Abstract

An unprecedented clean interconversion between a novel bis(mu-thiolato)dicopper(II) complex (1) and a disulfide-bridged dicopper(I) complex (3) through a disulfide-bridged (mu-chloro)dicopper(I) complex (2) mediated by chloride ion has been established for the first time, providing a new redox chemistry of the transition metal-sulfur complexes. Crystal structures of 1 and 3 as well as spectroscopic features of the compounds are reported.

Entities:  

Year:  2002        PMID： 12381181     DOI： 10.1021/ja027397m

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

Review 1.  Cu(A) centers and their biosynthetic models in azurin.

Authors:  Masha G Savelieff; Yi Lu
Journal:  J Biol Inorg Chem       Date:  2010-02-19       Impact factor: 3.358

2.  Reaction of N-Acetylcysteine with Cu2+: Appearance of Intermediates with High Free Radical Scavenging Activity: Implications for Anti-/Pro-Oxidant Properties of Thiols.

Authors:  Ivan Valent; Lucie Bednárová; Igor Schreiber; Juraj Bujdák; Katarína Valachová; Ladislav Šoltés
Journal:  Int J Mol Sci       Date:  2022-05-31       Impact factor: 6.208

3.  Redox Interconversion between Cobalt(III) Thiolate and Cobalt(II) Disulfide Compounds.

Authors:  Feng Jiang; Maxime A Siegler; Xiaobo Sun; Lin Jiang; Célia Fonseca Guerra; Elisabeth Bouwman
Journal:  Inorg Chem       Date:  2018-07-19       Impact factor: 5.165
  3 in total

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