Literature DB >> 12377025

A tetranuclear heterobimetallic square formed from the cooperative ligand binding properties of square planar and tetrahedral metal centers.

Nathan C Gianneschi1, Chad A Mirkin, Lev N Zakharov, Arnold L Rheingold.   

Abstract

Reaction of Rh(I) and Zn(II) metal centers with a ligand containing salicylaldiminato and thioether-phosphine moieties resulted in the formation of a tetranuclear heterobimetallic molecular square. The directionality required to form these structures is imparted by both the tetrahedral and square planar metal centers acting in concert with one another.

Entities:  

Year:  2002        PMID： 12377025     DOI： 10.1021/ic025875o

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  2 in total

1.  Chelating effect as a driving force for the selective formation of heteroligated Pt(II) complexes with bidentate phosphino-chalcoether ligands.

Authors:  Mari S Rosen; Alexander M Spokoyny; Charles W Machan; Charlotte Stern; Amy Sarjeant; Chad A Mirkin
Journal:  Inorg Chem       Date:  2010-12-28       Impact factor: 5.165

Review 2.  Supramolecular coordination: self-assembly of finite two- and three-dimensional ensembles.

Authors:  Rajesh Chakrabarty; Partha Sarathi Mukherjee; Peter J Stang
Journal:  Chem Rev       Date:  2011-08-24       Impact factor: 60.622
  2 in total

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