| Literature DB >> 12370896 |
Abstract
The chemical properties of gold are strongly influenced by relativistic effects. One example is the large electronegativity of Au, which qualitatively explains the stability of (solid or liquid) cesium auride, Cs(+)Au(-), and other systems with Au(-) ions. An especially impressive compound is CsAu.NH(3), the structure and bonding of which are discussed. Future possibilities for finding further aurides are outlined.Entities:
Year: 2002 PMID： 12370896 DOI： 10.1002/1521-3773(20021004)41:19<3573::AID-ANIE3573>3.0.CO;2-R
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336