Literature DB >> 12359928

catena-Poly[[[aqua(2-methyl-4-oxo-4H-pyran-3-olato-kappaO3,O4)copper(II)]-mu-chloro] monohydrate].

Mamiko Odoko1, Kyouta Yamamoto, Nobuo Okabe.   

Abstract

In the title complex, [Cu(C(6)H(5)O(3))Cl(H(2)O)].H(2)O(n), the Cu(II) atom has a deformed square-pyramidal coordination geometry formed by two O atoms of the maltolate ligand, two bridging Cl atoms and the coordinated water O atom. The Cu atoms are bridged by Cl atoms to form a polymeric chain. The deprotonated hydroxyl and ketone O atoms of the maltolate ligand form a five-membered chelate ring with the Cu atom. Stacking interactions and hydrogen bonds exist in the crystal.

Entities:  

Year:  2002        PMID: 12359928     DOI: 10.1107/s0108270102015226

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  3 in total

1.  Chlorido(2-methyl-4-oxo-4H-pyran-3-olato-κO,O)(1,10-phenanthroline-κN,N')copper(II).

Authors:  Kong Wai Tan; Chew Hee Ng; Mohd Jamil Maah; Seik Weng Ng
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-07-31

2.  (2-Methyl-4-oxo-4H-pyran-3-olato-κO,O)bis-(triphenyl-phosphane-κP)copper(I)-triphenyl-phosphane-methanol (1/1/1).

Authors:  Fabian M A Muller; Theunis J Muller; Gideon Steyl
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-04-13

3.  Crystal structure of [bis-(2-amino-ethyl-κN)(2-{[4-(tri-fluoro-meth-yl)benzyl-idene]amino}-eth-yl)amine-κN]di-chlorido-copper(II).

Authors:  Katherine A Bussey; Annie R Cavalier; Margaret E Mraz; Ashley S Holderread; Kayode D Oshin; Allen G Oliver; Matthias Zeller
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2016-01-01
  3 in total

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