Literature DB >> 12358511

Stable (aryl)(phosphino)carbenes: new ligands for transition metals.

Emmanuelle Despagnet1, Karinne Miqueu, Heinz Gornitzka, Philip W Dyer, Didier Bourissou, Guy Bertrand.   

Abstract

The first direct complexation of a stable phosphino carbene to a transition metal center is described. Both eta1- and eta2-coordination modes have been characterized spectroscopically. The Fischer-type structure of the eta1-carbene rhodium complex was revealed by an X-ray diffraction study.

Entities:  

Year:  2002        PMID： 12358511     DOI： 10.1021/ja027201i

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  6 in total

1.  Transient palladadiphosphanylcarbenes: singlet carbenes with an "inverse" electronic configuration (p(pi)2 instead of sigma2) and unusual transannular metal-carbene interactions (piC-->Pd donation and sigmaPd-->C back-donation).

Authors:  Joan Vignolle; Heinz Gornitzka; Laurent Maron; Wolfgang W Schoeller; Didier Bourissou; Guy Bertrand
Journal:  J Am Chem Soc       Date:  2007-01-31       Impact factor: 15.419

2.  A Brief Survey of our Contribution to Stable Carbene Chemistry.

Authors:  David Martin; Mohand Melaimi; Michele Soleilhavoup; Guy Bertrand
Journal:  Organometallics       Date:  2011-09-22       Impact factor: 3.876

Review 3.  Stable cyclic carbenes and related species beyond diaminocarbenes.

Authors:  Mohand Melaimi; Michèle Soleilhavoup; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2010-11-15       Impact factor: 15.336

4.  A persistent P,N-heterocyclic carbene.

Authors:  Guido D Frey; Maoying Song; Jean-Baptiste Bourg; Bruno Donnadieu; Michele Soleilhavoup; Guy Bertrand
Journal:  Chem Commun (Camb)       Date:  2008-09-05       Impact factor: 6.222

5.  Stable P-heterocyclic carbenes: scope and limitations.

Authors:  Jason D Masuda; David Martin; Celine Lyon-Saunier; Antoine Baceiredo; Heinz Gornitzka; Bruno Donnadieu; Guy Bertrand
Journal:  Chem Asian J       Date:  2007-01-08

6.  A Stable (Amino)(Phosphino)Carbene as bidentate ligand for Palladium and Nickel Complexes: Synthesis, Structure, and Catalytic Activity.

Authors:  Emmanuelle Teuma; Céline Lyon-Saunier; Heinz Gornitzka; Gérard Mignani; Antoine Baceiredo; Guy Bertrand
Journal:  J Organomet Chem       Date:  2005       Impact factor: 2.369
  6 in total

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