Literature DB >> 12354011

AlCl(3) x 6H(2)O/KI/H(2)O/CH(3)CN: a new alternate system for dehydration of oximes and amides in hydrated media.

Monalisa Boruah1, Dilip Konwar.   

Abstract

Dehydration of oximes and amides to nitriles was carried out using the AlCl(3) x 6H(2)O/KI/H(2)O/CH(3)CN system. It produced isoquinoline derivatives 8a-c (Bischler Naperialski reaction) when reacted with amides 7a-c in hydrated media. Also, the keto oximes produced anilides (Beckmann rearrangement) with the system under the same reaction conditions.

Entities:  

Year:  2002        PMID: 12354011     DOI: 10.1021/jo020005+

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  1 in total

1.  Visible Light-Promoted Beckmann Rearrangements: Separating Sequential Photochemical and Thermal Phenomena in a Continuous Flow Reactor.

Authors:  Yuesu Chen; David Cantillo; C Oliver Kappe
Journal:  European J Org Chem       Date:  2019-03-08
  1 in total

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