Comparison of microwave-assisted extraction and waste extraction test (WET) preparation for inductively coupled plasma spectroscopic analyses of waste samples.

The Waste Extraction Test (WET) is used in California as a complement to the Toxicity Characteristic Leaching Procedure (TCLP). The WET protocol consists of shaking a sample with citrate buffer and determining the metal content in the solution produced. This procedure requires a 1-to-10 waste-to-liquid ratio and 48 h for extraction. Although the WET protocol proves to be very useful, it is a time-consuming step in the determination of leaching and mobility. Therefore, a microwave extraction procedure was optimized to emulate the relative extraction efficiency obtained by the WET protocol. Lead, arsenic, and copper concentrations were measured by inductively coupled plasma mass or atomic spectrometry (ICP-MS or ICP-AES), following a strict quality assurance protocol. Results obtained with this new methodology were statistically comparable to those obtained by the WET protocol. This microwave extraction approach proved simple and fast, reducing sample treatment by almost 280%. A significant reduction also occurs in waste production, materials, labor, and chemical usage. Therefore, the microwave extraction procedure is recommended as a rapid and cost effective monitoring tool for waste samples when combined with or supplemented by the traditional WET protocol.