| Literature DB >> 12271635 |
Daniel J Mindiola1, Gregory L Hillhouse.
Abstract
The imido complex (dtbpe)Ni(N(2,6-(CHMe2)2C6H3)) reacts with CO and CNCH2Ph with addition at the Ni-N bond to give (dtbpe)Ni(C,N:eta 2-C(O)N(2,6-(CHMe2)2C6H3)) and (dtbpe)Ni(C,N:eta 2-C(NCH2Ph)N(2,6-(CHMe2)2C6H3)); both complexes react further with CO to liberate the isocyanate and carbodiimide ligands with formation of (dtbpe)Ni(CO)2.Entities:
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Year: 2002 PMID： 12271635 DOI： 10.1039/b204846a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222