Literature DB >> 12240381

Cerium masquerading as a group 4 element: synthesis, structure and computational characterisation of [CeCl(N(SiMe3)2)3].

O Eisenstein1, P B Hitchcock, A G Hulkes, M F Lappert, L Maron.   

Abstract

Oxidation of the three-coordinate cerium amide [Ce(N-(SiMe3)2)3] with TeCl4 in toluene solution yields purple, diamagnetic [CeCl(N(SiMe3)2)3], whose structure has been examined by X-ray crystallographic and computational methods.

Entities:  

Year:  2001        PMID: 12240381     DOI: 10.1039/b103634n

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Synthesis of a terminal Ce(iv) oxo complex by photolysis of a Ce(iii) nitrate complex.

Authors:  Mikiyas K Assefa; Guang Wu; Trevor W Hayton
Journal:  Chem Sci       Date:  2017-09-27       Impact factor: 9.825

2.  The role of dynamic ligand exchange in the oxidation chemistry of cerium(iii).

Authors:  Jerome R Robinson; Yusen Qiao; Jun Gu; Patrick J Carroll; Patrick J Walsh; Eric J Schelter
Journal:  Chem Sci       Date:  2016-03-23       Impact factor: 9.825

  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.