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Literature DB >> 12240372

Tuning metal coordination number by ancillary ligand steric effects: synthesis of a three-coordinate iron(II) complex.

J M Smith¹, R J Lachicotte, P L Holland.

Abstract

The coordination number of the metal in iron(II) beta-diketiminate complexes can be tuned through the size of the alkyl substituents on the ligand backbone.

Entities: Chemical

Year: 2001 PMID： 12240372 DOI： 10.1039/b103635c

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

13 in total

1. Ligand structural effects on Cu2S2 bonding and reactivity in side-on disulfido-bridged dicopper complexes.

Authors: Eric C Brown; Itsik Bar-Nahum; John T York; Nermeen W Aboelella; William B Tolman
Journal: Inorg Chem Date: 2007-01-22 Impact factor: 5.165

2. Quantitative geometric descriptions of the belt iron atoms of the iron-molybdenum cofactor of nitrogenase and synthetic iron(II) model complexes.

Authors: Javier Vela; Jordi Cirera; Jeremy M Smith; Rene J Lachicotte; Christine J Flaschenriem; Santiago Alvarez; Patrick L Holland
Journal: Inorg Chem Date: 2007-01-08 Impact factor: 5.165

3. Effects of Ligand Halogenation on the Electron Localization, Geometry and Spin State of Low-Coordinate (β-Diketiminato)iron Complexes.

Authors: Sarina M Bellows; William W Brennessel; Patrick L Holland
Journal: Eur J Inorg Chem Date: 2016-05-30 Impact factor: 2.524

4. [N,N'-Bis(2,6-diisopropyl-phen-yl)pentane-2,4-diamine-(1-)-2κN,N']-μ(2)-chlorido-1:2κCl:Cl-chlorido-2κCl-bis-(1,2-di-methoxy-ethane-1κO,O')iron(II)lithium.

Authors: Rafał Grubba; Lukasz Ponikiewski; Lukasz Tomorowicz; Jerzy Pikies
Journal: Acta Crystallogr Sect E Struct Rep Online Date: 2010-05-26

Tuning metal coordination number by ancillary ligand steric effects: synthesis of a three-coordinate iron(II) complex.

1. Ligand structural effects on Cu2S2 bonding and reactivity in side-on disulfido-bridged dicopper complexes.

2. Quantitative geometric descriptions of the belt iron atoms of the iron-molybdenum cofactor of nitrogenase and synthetic iron(II) model complexes.

3. Effects of Ligand Halogenation on the Electron Localization, Geometry and Spin State of Low-Coordinate (β-Diketiminato)iron Complexes.

4. [N,N'-Bis(2,6-diisopropyl-phen-yl)pentane-2,4-diamine-(1-)-2κN,N']-μ(2)-chlorido-1:2κCl:Cl-chlorido-2κCl-bis-(1,2-di-methoxy-ethane-1κO,O')iron(II)lithium.

5. Cobalt-Magnesium and Iron-Magnesium Complexes with Weakened Dinitrogen Bridges.

6. The reactivity patterns of low-coordinate iron-hydride complexes.

7. Mechanistic insight into N=N cleavage by a low-coordinate iron(II) hydride complex.

8. Ligand dependence of binding to three-coordinate Fe(II) complexes.

9. Tuning steric and electronic effects in transition-metal β-diketiminate complexes.

Review 10. Electronic structure and reactivity of three-coordinate iron complexes.