| Literature DB >> 12240343 |
M J Gaunt1, J Yu, J B Spencer.
Abstract
The allylic hydrogen is found to have a dramatic effect on the regioselectivity of the Wacker oxidation, leading to the postulation that an agostic hydrogen or enyl (sigma + pi) complex helps to stabilise the key intermediate.Entities:
Year: 2001 PMID： 12240343 DOI： 10.1039/b103066n
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222