| Literature DB >> 12240340 |
M Okamoto1, K Miyazaki, A Kado, E Suzuki.
Abstract
Hexamethyldisiloxane and hexamethylcyclotrisiloxane were almost completely deoligomerized with dimethyl carbonate over alumina-supported potassium fluoride catalyst to form methoxytrimethylsilane (85% yield) and dimethoxydimethylsilane (94% yield), respectively, and moreover the addition of a small amount of methanol to the hexamethyldisiloxane deoligomerization reaction enhanced the methoxytrimethylsilane yield to 98%.Entities:
Year: 2001 PMID： 12240340 DOI： 10.1039/b104371b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222