Literature DB >> 12240237

The first observation of the [Cp3Mn]- anion; structures of hexagonal [(eta 2-Cp)3MnK.1.5thf] and ion-separated [(eta 2-Cp)3Mn]2[Mg(thf)6].2thf.

A D Bond1, R A Layfield, J A MacAllister, M McPartlin, J M Rawson, D S Wright.   

Abstract

Hexagonal [(eta 2-Cp)3MnK.1.5thf] 1 and ion-separated [(eta 2-Cp)3Mn]2[Mg(thf)6].2thf 2 are obtained from reactions of CpK and Cp2Mg, respectively, with manganocene, Cp2Mn; they are the first complexes to be structurally characterised containing the [Cp3Mn]- anion.

Entities:  

Year:  2001        PMID: 12240237     DOI: 10.1039/b106366a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Exposing the hidden complexity of stoichiometric and catalytic metathesis reactions by elucidation of Mg-Zn hybrids.

Authors:  Eva Hevia; Jonathan Z Chua; Pablo García-Alvarez; Alan R Kennedy; Matthew D McCall
Journal:  Proc Natl Acad Sci U S A       Date:  2010-03-08       Impact factor: 11.205

  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.