Literature DB >> 12240165

The first Ru(II)-catalysed asymmetric hydrogen transfer reduction of aromatic ketones in aqueous media.

H Y Rhyoo1, H J Park, Y K Chung.   

Abstract

The first water-soluble asymmetric hydrogen-transfer ruthenium(II) catalyst system consisting of [Ru(p-cymene)Cl2]2, (S)-proline amide, and sodium formate, which gives high conversion rates with high ee values up to 95.3% and is reusable, has been developed.

Entities:  

Year:  2001        PMID: 12240165     DOI: 10.1039/b106130p

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Artificial metalloenzymes based on biotin-avidin technology for the enantioselective reduction of ketones by transfer hydrogenation.

Authors:  Christophe Letondor; Nicolas Humbert; Thomas R Ward
Journal:  Proc Natl Acad Sci U S A       Date:  2005-03-16       Impact factor: 11.205

2.  Coordinating Chiral Ionic Liquids: Design, Synthesis, and Application in Asymmetric Transfer Hydrogenation under Aqueous Conditions.

Authors:  Maria Vasiloiu; Peter Gaertner; Ronald Zirbs; Katharina Bica
Journal:  European J Org Chem       Date:  2015-02-20
  2 in total

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