Literature DB >> 12240104

Observation of a P/M interconversion of a gold-phosphine helicate via 31P NMR.

W Schuh1, H Kopacka, K Wurst, P Peringer.   

Abstract

Ligands containing P-CH2-CH2-P elements have been shown to form double-stranded helicates whose axis consists of gold atoms with Au...Au contacts; the interconversion of the P and M forms of the helicate [Au3(mu-pp2)2](OTf)3 (pp2 = PhP(CH2CH2PPh2)2) is monitored via 31P NMR.

Entities:  

Year:  2001        PMID: 12240104     DOI: 10.1039/b106058a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Bis[μ-1,2-bis-(diphenyl-phosphino)ethane-κP:P']digold(I)(Au-Au) bis-(trifluoro-methane-sulfonate) acetonitrile disolvate.

Authors:  Christoph E Strasser; Stephanie Cronje; Helgard G Raubenheimer
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-07-11

2.  Gold(I/III)-Phosphine Complexes as Potent Antiproliferative Agents.

Authors:  Jong Hyun Kim; Evan Reeder; Sean Parkin; Samuel G Awuah
Journal:  Sci Rep       Date:  2019-08-26       Impact factor: 4.379

  2 in total

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