Literature DB >> 12240095

Recent advances in solventless organic reactions: towards benign synthesis with remarkable versatility.

G W Cave1, C L Raston, J L Scott.   

Abstract

A paradigm shift away from using solvents in organic synthesis as solventless reactions can lead to improved outcomes, and more benign synthetic procedures, in for example aldol condensation reactions, sequential aldol and Michael addition reactions en route to Kröhnke type pyridines, reactions leading to 3-carboxycoumarins, benzylidenes, 4-aryl-1,4-dihydropyridines and 2-aryl-1,2,3,4-tetrahydroquinazolines, and oligomerisation reactions for the synthesis of cavitands; kinetic considerations for the reaction of two solids can only be explained if a eutectic melt is formed during the reaction.

Year:  2001        PMID： 12240095

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  22 in total

1.  A green chemistry approach to asymmetric catalysis: solvent-free and highly concentrated reactions.

Authors:  Patrick J Walsh; Hongmei Li; Cecilia Anaya de Parrodi
Journal:  Chem Rev       Date:  2007-05-27       Impact factor: 60.622

2.  Self-associated, "distillable" ionic media.

Authors:  Ulf P Kreher; Anthony E Rosamilia; Colin L Raston; Janet L Scott; Christopher R Strauss
Journal:  Molecules       Date:  2004-05-31       Impact factor: 4.411

3.  Highly concentrated catalytic asymmetric allylation of ketones.

Authors:  Alfred J Wooten; Jeung Gon Kim; Patrick J Walsh
Journal:  Org Lett       Date:  2007-02-01       Impact factor: 6.005

4.  A mild and efficient method for the synthesis of a new class of furo[3,2-c]chromenes in aqueous media.

Authors:  Mohammad A Khalilzadeh; Zinatossadat Hossaini; Faramarz Rostami Charati; Sara Hallajian; Mehdi Rajabi
Journal:  Mol Divers       Date:  2010-08-25       Impact factor: 2.943

Review 5.  Mechanochemistry: New Tools to Navigate the Uncharted Territory of "Impossible" Reactions.

Authors:  Federico Cuccu; Lidia De Luca; Francesco Delogu; Evelina Colacino; Niclas Solin; Rita Mocci; Andrea Porcheddu
Journal:  ChemSusChem       Date:  2022-07-21       Impact factor: 9.140

6.  Environmentally Benign Lewis Acid Promoted [2+3]-Dipolar Cycloaddition Reactions of Nitrile Imines with Alkenes in Water.

Authors:  Sureshbabu Dadiboyena; Ashton T Hamme
Journal:  European J Org Chem       Date:  2013-11

7.  Solvent-free and time-efficient Suzuki-Miyaura reaction in a ball mill: the solid reagent system KF-Al(2)O(3) under inspection.

Authors:  Franziska Bernhardt; Ronald Trotzki; Tony Szuppa; Achim Stolle; Bernd Ondruschka
Journal:  Beilstein J Org Chem       Date:  2010-01-22       Impact factor: 2.883

8.  Desorption electrospray ionization mass spectrometry for monitoring the kinetics of Baeyer-Villiger solid-state organic reactions.

Authors:  Ying Xie; Li-Fang He; Shui-Chao Lin; Hai-Feng Su; Su-Yuan Xie; Rong-Bin Huang; Lan-Sun Zheng
Journal:  J Am Soc Mass Spectrom       Date:  2009-07-18       Impact factor: 3.109

9.  An efficient protocol for the synthesis of highly sensitive indole imines utilizing green chemistry: optimization of reaction conditions.

Authors:  Bushra Nisar; Syeda Laila Rubab; Abdul Rauf Raza; Sobia Tariq; Ayesha Sultan; Muhammad Nawaz Tahir
Journal:  Mol Divers       Date:  2018-04-11       Impact factor: 2.943

10.  Supported heteropoly acids offering strong option for efficient and cleaner processing for the synthesis of imidazole derivatives under solvent-free condition.

Authors:  Ezzat Rafiee; Houri Mahdavi; Mohammad Joshaghani
Journal:  Mol Divers       Date:  2010-01-26       Impact factor: 2.943
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