Literature DB >> 12240081

Preparation, structure and catalytic properties of a binuclear Pd(0) complex with bridging silylene ligands.

A Fürstner1, H Krause, C W Lehmann.   

Abstract

In contrast to the N-heterocyclic carbene (NHC) 1, the homologous N-heterocyclic silylene (NHS) 4 acts as a bridging ligand to Pd(0), giving rise to the dinuclear complex 5 which is catalytically active in Suzuki reactions.

Entities:  

Year:  2001        PMID： 12240081     DOI： 10.1039/b108132b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Coordination chemistry at carbon.

Authors:  Manuel Alcarazo; Christian W Lehmann; Anakuthil Anoop; Walter Thiel; Alois Fürstner
Journal:  Nat Chem       Date:  2009-06-14       Impact factor: 24.427

2.  A Free Silanide from Nucleophilic Substitution at Silicon(II).

Authors:  Léon Witteman; Tim Evers; Martin Lutz; Marc-Etienne Moret
Journal:  Chemistry       Date:  2018-04-30       Impact factor: 5.236

3.  Synthesis and Complexation of a Free Germanide Bearing a Tridentate N-Heterocyclic Substituent.

Authors:  Léon Witteman; Cody B van Beek; Oscar N van Veenhuizen; Martin Lutz; Marc-Etienne Moret
Journal:  Organometallics       Date:  2019-01-09       Impact factor: 3.876

4.  N-Heterocyclic Silylenes as Ligands in Transition Metal Carbonyl Chemistry: Nature of Their Bonding and Supposed Innocence.

Authors:  Mirjam J Krahfuß; Jörn Nitsch; F Matthias Bickelhaupt; Todd B Marder; Udo Radius
Journal:  Chemistry       Date:  2020-07-27       Impact factor: 5.236
  4 in total

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