Literature DB >> 12240065

Chelating alkoxy-N-heterocyclic carbene complexes of silver and copper.

P L Arnold1, A C Scarisbrick, A J Blake, C Wilson.   

Abstract

Incorporation of an alkoxide functional group into an N-heterocyclic carbene (NHC) ligand allows the synthesis of the first anionic NHC chelating ligands, which react to give the first neutral, molecular silver(I) alkoxide carbene complex, and a copper(I) derivative containing the first nonmacrocyclic, square planar Cu(I) centres.

Entities:  

Year:  2001        PMID: 12240065     DOI: 10.1039/b107855k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  5 in total

1.  Heterobimetallic activation of dioxygen: characterization and reactivity of novel Cu(I)-Ge(II) complexes.

Authors:  John T York; Victor G Young; William B Tolman
Journal:  Inorg Chem       Date:  2006-05-15       Impact factor: 5.165

2.  Hydrogen Bonds Dictate the Coordination Geometry of Copper: Characterization of a Square-Planar Copper(I) Complex.

Authors:  Eric W Dahl; Nathaniel K Szymczak
Journal:  Angew Chem Int Ed Engl       Date:  2016-01-28       Impact factor: 15.336

3.  Expansion of the (BB) 〉metallacycle with coinage metal cations: formation of B-M-Ru-B (M = Cu, Ag, Au) dimetalacyclodiboryls.

Authors:  Bennett J Eleazer; Mark D Smith; Alexey A Popov; Dmitry V Peryshkov
Journal:  Chem Sci       Date:  2018-02-05       Impact factor: 9.825

4.  Postsynthetic ionization of an imidazole-containing metal-organic framework for the cycloaddition of carbon dioxide and epoxides.

Authors:  Jun Liang; Rui-Ping Chen; Xiu-Yun Wang; Tao-Tao Liu; Xu-Sheng Wang; Yuan-Biao Huang; Rong Cao
Journal:  Chem Sci       Date:  2016-11-02       Impact factor: 9.825

Review 5.  Functionalised N-Heterocyclic Carbene Ligands in Bimetallic Architectures.

Authors:  Kieren J Evans; Stephen M Mansell
Journal:  Chemistry       Date:  2020-03-18       Impact factor: 5.236

  5 in total

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