| Literature DB >> 12224918 |
Shu Takahashi1, Hirohiko Miura, Hitoshi Kasai, Shuji Okada, Hidetoshi Oikawa, Hachiro Nakanishi.
Abstract
Topochemical [2 + 2] cycloaddition polymerization of methyl p-phenylenediacrylate and 2,5-distyrylpyridine in nanocrystals, prepared by the reprecipitation method, were investigated in comparison with those in bulk crystals. The bulk single crystals, larger than 1 mum in size, broke into microcrystals with variety of size and shape in the course of polymerization. Interestingly, however, these nanocrystals show single-crystal-to-single-crystal transformation.Entities:
Year: 2002 PMID: 12224918 DOI: 10.1021/ja026564f
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419