Literature DB >> 12205387

The stable inner salt 2,2-dimorpholino-2-ethylium-1-dithioate.

Takashi Fujihara1, Takeshi Ohba, Akira Nagasawa, Juzo Nakayama, Kenji Yoza.   

Abstract

The title compound, C(10)H(16)N(2)O(2)S(2), is considered to maintain an inner-salt structure in the crystal, where the planes of the carbenium and the thiocarboxylate moieties are nearly perpendicular to each other [77 (2) degrees ], and the backbone C-C bond length [N(2)C-CS(2) 1.510 (2) A] is significantly shorter than a normal C-C single-bond length.

Entities:  

Year:  2002        PMID: 12205387     DOI: 10.1107/S0108270102013756

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  2-{[2,2-Bis(diethyl-amino)-ethan-2-ylium-thio-yl]sulfan-yl}-1,1-bis-(diethyl-amino)-ethyl-ium bis-(perchlorate).

Authors:  Keiji Ohno; Tomoaki Sugaya; Takashi Fujihara; Akira Nagasawa
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-08-23
  1 in total

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