| Literature DB >> 12203641 |
M H Huynh1, P S White, C A Carter, T J Meyer.
Abstract
Oxo-like reactivity exists for a new series of osmium complexes such as [Os(IV) (bpy)(Cl)3 (NCN)](-) (bpy=2,2'-bipyridine, see structure) containing the cyanoimido ligand. This ligand is formed directly at the metal center by the reaction of Os(VI) -nitrido precursors with tetraethylammonium cyanide. In the cyanoimido complexes there is an extensive electron-transfer chemistry at the metal center and an extensive functional-group chemistry based on the ligand.Entities:
Keywords: acylation; alkylation; cyanoimido ligands; osmium; protonation
Year: 2001 PMID： 12203641 DOI： 10.1002/1521-3773(20010817)40:16<3037::AID-ANIE3037>3.0.CO;2-0
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336