| Literature DB >> 12203637 |
J Tirreé1, D Gudat, M Nieger, E Niecke.
Abstract
The tautomeric four-membered-ring P-N heterocycles 1, 2, and 3 can be interconverted; the formation of the cyclodiphosph(V)azene 1 is enthalpically and entropically favored. The crystal structures of the tautomers 1 and 3 have been determined and indications are given regarding the mechanism of the interconversion.Entities:
Keywords: NMR spectroscopy; phosphorus; phosphorus heterocycles; tautomerism
Year: 2001 PMID： 12203637 DOI： 10.1002/1521-3773(20010817)40:16<3025::AID-ANIE3025>3.0.CO;2-E
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336