Literature DB >> 12201743

Biaryl synthesis from two different aryl halides with tri(2-furyl)germane.

Tomoaki Nakamura1, Hidenori Kinoshita, Hiroshi Shinokubo, Koichiro Oshima.   

Abstract

[reaction: see text] The coupling reaction of germanium compounds with aryl halides has been developed. The Pd(0)-catalyzed reaction of aryl halides with tri(2-furyl)germane provides aryltri(2-furyl)germanes in good yield. The cross-coupling reaction of aryltri(2-furyl)germanes with aryl halides is achieved. This allows facile synthesis of unsymmetrical biaryls from two different aryl halides.

Entities:  

Year:  2002        PMID： 12201743     DOI： 10.1021/ol026613t

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  9 in total

1.  Fluoride-promoted cross-coupling of chloro(mono-, di-, or triphenyl)germanes with aryl halides in "moist" toluene. Multiple transfer of the phenyl group from organogermane substrates and comparison of the coupling efficiencies of chloro(phenyl)germanes with their corresponding stannane and silane counterparts.

Authors:  Jean-Philippe Pitteloud; Zun-Ting Zhang; Yong Liang; Laura Cabrera; Stanislaw F Wnuk
Journal:  J Org Chem       Date:  2010-11-10       Impact factor: 4.354

Review 2.  Inorganometallics (Transition Metal-Metalloid Complexes) and Catalysis.

Authors:  Bogdan Marciniec; Cezary Pietraszuk; Piotr Pawluć; Hieronim Maciejewski
Journal:  Chem Rev       Date:  2021-12-30       Impact factor: 60.622

3.  Arylchlorogermanes/TBAF/"moist" toluene: a promising combination for Pd-catalyzed Germyl-Stille cross-coupling.

Authors:  Zun-Ting Zhang; Jean-Philippe Pitteloud; Laura Cabrera; Yong Liang; Myrdich Toribio; Stanislaw F Wnuk
Journal:  Org Lett       Date:  2010-02-19       Impact factor: 6.005

4.  Vinyl Tris(trimethylsilyl)silanes: Substrates for Hiyama Coupling.

Authors:  Zhizhong Wang; Jean-Philippe Pitteloud; Lucresia Montes; Magdalena Rapp; Djenny Derane; Stanislaw F Wnuk
Journal:  Tetrahedron       Date:  2008-05-26       Impact factor: 2.457

5.  Synthesis, Structure, Thermal Behavior and cis/trans Isomerization of 2,2'-(EMe₃)₂ (E = C, Si, Ge, Sn) Substituted Azobenzenes.

Authors:  Jonas Hoffmann; Thomas Josef Kuczmera; Enno Lork; Anne Staubitz
Journal:  Molecules       Date:  2019-01-15       Impact factor: 4.411

6.  Gold-Catalyzed C-H Functionalization with Aryl Germanes.

Authors:  Christoph Fricke; Amit Dahiya; William B Reid; Franziska Schoenebeck
Journal:  ACS Catal       Date:  2019-08-30       Impact factor: 13.084

7.  Modular Generation of (Iodinated) Polyarenes Using Triethylgermane as Orthogonal Masking Group.

Authors:  Tatjana Kreisel; Marvin Mendel; Adele E Queen; Kristina Deckers; Daniel Hupperich; Julian Riegger; Christoph Fricke; Franziska Schoenebeck
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-21       Impact factor: 16.823

8.  Modular and Selective Arylation of Aryl Germanes (C-GeEt3 ) over C-Bpin, C-SiR3 and Halogens Enabled by Light-Activated Gold Catalysis.

Authors:  Grant J Sherborne; Avetik G Gevondian; Ignacio Funes-Ardoiz; Amit Dahiya; Christoph Fricke; Franziska Schoenebeck
Journal:  Angew Chem Int Ed Engl       Date:  2020-06-12       Impact factor: 15.336

Review 9.  Orthogonal Nanoparticle Catalysis with Organogermanes.

Authors:  Christoph Fricke; Grant J Sherborne; Ignacio Funes-Ardoiz; Erdem Senol; Sinem Guven; Franziska Schoenebeck
Journal:  Angew Chem Int Ed Engl       Date:  2019-10-23       Impact factor: 15.336
  9 in total

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