Literature DB >> 12201709

New palladium carbene catalysts for the Heck reaction of aryl chlorides in ionic liquids.

Kumaravel Selvakumar1, Alexander Zapf, Matthias Beller.   

Abstract

[reaction: see text] The Heck reaction of aryl chlorides was investigated in the presence of defined monocarbenepalladium(0) complexes. Activated and nonactivated aryl chlorides provide the corresponding cinnamic esters and stilbenes in (n)Bu(4)NBr as a ionic liquid in good to excellent yields.

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Year:  2002        PMID: 12201709     DOI: 10.1021/ol020103h

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  6 in total

1.  A rapid microwave protocol for Heck vinylation of aryl chlorides under air.

Authors:  Gopal K Datta; Karl S A Vallin; Mats Larhed
Journal:  Mol Divers       Date:  2003       Impact factor: 2.943

2.  Pd-catalyzed decarboxylative Heck vinylation of 2-nitrobenzoates in the presence of CuF₂.

Authors:  Lukas J Gooßen; Bettina Zimmermann; Thomas Knauber
Journal:  Beilstein J Org Chem       Date:  2010-05-03       Impact factor: 2.883

3.  Organotrifluoroborates and monocoordinated palladium complexes as catalysts--a perfect combination for Suzuki-Miyaura coupling.

Authors:  Gary A Molander; Belgin Canturk
Journal:  Angew Chem Int Ed Engl       Date:  2009       Impact factor: 15.336

4.  Ruthenium-Catalyzed E-Selective Alkyne Semihydrogenation with Alcohols as Hydrogen Donors.

Authors:  Andreas Ekebergh; Romain Begon; Nina Kann
Journal:  J Org Chem       Date:  2020-02-19       Impact factor: 4.354

5.  Chloro({2-[mesityl(quinolin-8-yl-κN)boryl]-3,5-dimethyl-phenyl}methyl-κC)palladium(II) as a catalyst for Heck reactions.

Authors:  Sem Raj Tamang; James D Hoefelmeyer
Journal:  Molecules       Date:  2015-07-17       Impact factor: 4.411

6.  N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed Mizoroki-Heck reaction of aryl chlorides with styrenes.

Authors:  Ting-Ting Gao; Ai-Ping Jin; Li-Xiong Shao
Journal:  Beilstein J Org Chem       Date:  2012-11-12       Impact factor: 2.883

  6 in total

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