| Literature DB >> 12196992 |
Jérôme Le Nôtre1, Luc Brissieux, David Sémeril, Christian Bruneau, Pierre H Dixneuf.
Abstract
The three component catalyst Ru3(CO)12/1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride/Cs2CO3 (molar ratio 1:3:6) successively promotes both allyl to vinyl isomerization and Claisen rearrangement from allyl homoallyl and diallyl ethers to selectively afford gamma,delta-unsaturated aldehydes.Entities:
Year: 2002 PMID: 12196992 DOI: 10.1039/b205805g
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222