Literature DB >> 12190416

What controls the thickness of wetting layers near bulk criticality?

Denis Fenistein1, Daniel Bonn, Salima Rafaï, Gerard H Wegdam, Jacques Meunier, Andrew O Parry, Margarida M Telo da Gama.   

Abstract

We study the thickness of wetting layers in the binary-liquid mixture cyclohexane methanol. Far from the bulk critical point, the wetting layer thickness is independent of temperature, resulting from the competition between van der Waals and gravitational forces. Upon approaching the bulk critical temperature [t=(T(c)-T)/T(c)-->0], we observe that the wetting layer thickness diverges as t(-beta) with effective critical exponent beta=0.23+/-0.06. This is characteristic of a broad, intermediate scaling regime for the crossover from van der Waals wetting to critical scaling. We predict beta=beta/3 approximately 0.11, with beta the usual bulk-order parameter critical exponent, showing a small but significant difference with experiment.

Entities:  

Year:  2002        PMID: 12190416     DOI: 10.1103/PhysRevLett.89.096101

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  4 in total

1.  Surface and bulk interchange energy in binary mixtures of chain molecules.

Authors:  E Sloutskin; E B Sirota; O Gang; X Z Wu; B M Ocko; M Deutsch
Journal:  Eur Phys J E Soft Matter       Date:  2004-02       Impact factor: 1.890

2.  Dimple coalescence and liquid droplets distributions during phase separation in a pure fluid under microgravity.

Authors:  Ana Oprisan; Sorinel A Oprisan; John J Hegseth; Yves Garrabos; Carole Lecoutre-Chabot; Daniel Beysens
Journal:  Eur Phys J E Soft Matter       Date:  2014-09-30       Impact factor: 1.890

3.  Pattern Evolution during Double Liquid-Vapor Phase Transitions under Weightlessness.

Authors:  Ana Oprisan; Yves Garrabos; Carole Lecoutre; Daniel Beysens
Journal:  Molecules       Date:  2017-06-09       Impact factor: 4.411

4.  Measuring the Transition Rates of Coalescence Events during Double Phase Separation in Microgravity.

Authors:  Ana Oprisan; Yves Garrabos; Carole Lecoutre; Daniel Beysens
Journal:  Molecules       Date:  2017-07-06       Impact factor: 4.411

  4 in total

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